Abstract: Condenser vacuum is a critical parameter affecting steam turbine generation efficiency. Each 1 kPa of vacuum loss caused by cooling water-side fouling increases heat rate by approximately 1%, directly raising generation costs. This article examines the formation mechanism of fouling resistance, quantifies the relationship between terminal temperature difference and vacuum degradation, and presents a systematic cleaning approach combining Sulfamic Acid chemical cleaning with high-pressure water jetting. A three-dimensional effectiveness evaluation framework covering vacuum recovery, terminal temperature difference improvement, and heat transfer coefficient enhancement is established. A case study of a 300 MW unit condenser demonstrates complete vacuum recovery from -88.5 kPa to -94.2 kPa after cleaning, providing a technical reference for establishing cleaning cycles and acceptance criteria.

1. Introduction

The steam turbine condenser is the core component of a power plant's cold-end system, and its vacuum level directly affects unit heat rate and generation output. During normal operation, scale deposits, silt, and microbial slime gradually accumulate on the inner walls of condenser tubes on the cooling water side, causing progressive deterioration in heat transfer efficiency—manifested as increased terminal temperature difference and decreased vacuum. Industry statistics indicate that each 1 kPa drop in condenser vacuum increases turbine heat rate by 0.8% to 1.2%. For a 300 MW unit, this translates to over a thousand tons of extra standard coal consumption annually. Restoring condenser vacuum through scientific cleaning methods and establishing a quantified effectiveness evaluation system is therefore a key energy-saving measure for power plants.

2. Mechanism of Condenser Vacuum Degradation

2.1 Formation of Fouling Resistance

Condenser circulating cooling water, sourced from rivers, lakes, or cooling tower recirculation systems, contains dissolved Ca2+, Mg2+, and HCO3- ions. At the tube wall surface, localized temperature increases reduce CaCO₃ solubility, causing precipitation and deposition as hard scale. Simultaneously, suspended solids, silt, and microbial growth in the cooling water form a soft fouling layer on tube surfaces. Together, these two types of fouling constitute the fouling resistance that impedes heat transfer from the steam side to the cooling water side.

2.2 Quantitative Relationship Between Fouling and Vacuum

Condenser vacuum is determined by the turbine exhaust temperature, which in turn equals the sum of cooling water inlet temperature, temperature rise, and terminal temperature difference. When tube fouling reduces the overall heat transfer coefficient, the terminal temperature difference increases, directly raising exhaust temperature and lowering vacuum under unchanged cooling water conditions. The table below shows typical variations in key condenser parameters under different fouling states:

Parameter Clean Light Fouling Moderate Fouling Heavy Fouling
Fouling Resistance (m²·K/W)≤0.9×10⁻⁴1.5~3.0×10⁻⁴3.0~6.0×10⁻⁴≥6.0×10⁻⁴
Terminal Temp. Diff. (°C)3~55~88~1212~18
Vacuum Loss (kPa)Baseline1.5~3.03.0~6.06.0~10.0
Heat Rate Increase (%)1.5~3.53.5~7.07.0~12.0

As shown above, condenser fouling severity exhibits a strong positive correlation with vacuum loss and heat rate increase. When fouling resistance exceeds 6.0×10⁻⁴ m²·K/W, unit economics have deteriorated significantly, and cleaning must be scheduled promptly.

3. Condenser Cleaning Solutions

3.1 Chemical Cleaning Formulation and Mechanism

Given that condenser tube fouling is predominantly carbonate scale, Sulfamic Acid is employed as the primary cleaning agent. Compared to traditional HCl cleaning, Sulfamic Acid causes significantly lower corrosion on copper and copper-alloy tubes. Combined with the high-efficiency copper corrosion inhibitor BTA, it achieves effective scale removal while maximizing tube material protection. The cleaning solution is circulated through the condenser water side in a closed loop, utilizing the chelating reaction between Sulfamic Acid and CaCO₃ to progressively dissolve hard scale into soluble salts for discharge.

Component Function
Sulfamic AcidPrimary cleaning agent; dissolves carbonate scale and iron oxides
BTACopper-alloy corrosion inhibitor; protects tube substrate
SurfactantSurface-active agent; reduces surface tension for enhanced penetration
Na₂CO₃pH adjustment during neutralization and passivation stages

3.2 High-Pressure Water Jetting as Supplementary Cleaning

For tubes mechanically blocked by silt, packing debris, or other obstructions, high-pressure water jetting is applied tube-by-tube prior to chemical cleaning. A flexible self-propelling nozzle is inserted from one tube end, using high-pressure water impact force to dislodge compacted hard scale and blockages. Another critical role of high-pressure water jetting is stripping the slime layer and biofilm from tube surfaces, creating conditions for the subsequent chemical cleaning solution to fully contact the hard scale.

3.3 Online vs. Offline Cleaning Selection

For units with scheduled outage windows, offline cleaning achieves the most thorough results—opening the condenser water chamber allows direct access to tube bundles, with chemical circulation and water jetting applied alternately. However, when prolonged shutdowns are not feasible during peak demand periods, online chemical cleaning is the more practical option. The cleaning agent is injected at the circulating water inlet, with dosing rate and circulating water pH carefully controlled. While the process takes longer, its impact on generation output is minimal.

4. Cleaning Effectiveness Evaluation Framework

4.1 Quantitative Evaluation Metrics

Cleaning effectiveness cannot be judged by visual tube surface inspection alone. A data-driven evaluation framework must be established:

(1) Vacuum Recovery: Under identical unit load and circulating water inlet temperature conditions, compare condenser vacuum before and after cleaning. Vacuum improvement magnitude is the most direct indicator of cleaning effectiveness. A post-cleaning vacuum of ≥95% of design value is generally required.

(2) Terminal Temperature Difference Improvement: Terminal difference = exhaust temperature - circulating water outlet temperature. After cleaning reduces tube wall thermal resistance, the terminal difference should decrease markedly. The improvement rate is calculated as (pre-cleaning TD - post-cleaning TD) / pre-cleaning TD × 100%. Acceptance criteria typically require ≥50% improvement.

(3) Heat Transfer Coefficient Enhancement: Calculate the overall heat transfer coefficient K value before and after cleaning through condenser heat balance. The post-cleaning K value typically recovers to 85%~95% of design specification.

(4) Circulating Water Temperature Rise: Under identical load, the post-cleaning inlet-to-outlet temperature rise should increase, indicating enhanced heat exchange capacity.

4.2 Recommended Acceptance Criteria

Metric Pass Standard Excellent Standard
Vacuum Recovery Rate≥90% of design≥95% of design
TD Improvement Rate≥50%≥70%
K Value Recovery Rate≥85% of design≥95% of design
Tube Clearance Rate≥98% of tubes100% of tubes

5. Case Study: 300 MW Power Plant Condenser

Equipment Overview: A 300 MW subcritical steam turbine unit equipped with a twin-pass surface condenser containing 18,500 copper tubes (HSn70-1A tin-brass). Circulating cooling water sourced from an open-loop river intake system. The unit had operated for 6 years without thorough cleaning; prior to shutdown, vacuum had degraded to -88.5 kPa (design value -95.0 kPa) with a terminal temperature difference of 15.2°C.

Cleaning Process: After unit shutdown, the condenser water chambers were opened. All 18,500 tubes were individually cleaned via high-pressure water jetting for blockage clearance and pre-flushing. A closed-loop circulation cleaning system was then set up, using Sulfamic Acid as the primary cleaning agent. Solution pH and copper ion concentration were monitored in real time throughout the process, with BTA inhibitor keeping copper tube corrosion rates within safe limits. Following chemical cleaning, Na₂CO₃ solution was applied for passivation treatment, and the system was thoroughly flushed with water to neutrality.

Cleaning Results:

Metric Before Cleaning After Cleaning Improvement
Condenser Vacuum-88.5 kPa-94.2 kPa+5.7 kPa
Terminal Temp. Diff.15.2°C5.1°C-10.1°C
TD Improvement Rate66.4%
Heat Transfer Coeff. K~1,850 W/(m²·K)~2,620 W/(m²·K)+41.6%
Tube Clearance Rate100%All clear

After cleaning, the condenser vacuum recovered to -94.2 kPa at 300 MW load, reaching 99.2% of the design value. The terminal temperature difference dropped sharply from 15.2°C to 5.1°C. Based on the estimate of approximately 3 g/kWh coal consumption reduction per 1 kPa vacuum improvement, this alone saves about 1,500 tons of standard coal annually. Tube corrosion inspection confirmed wall thickness loss remained within safety margins, demonstrating excellent compatibility of the Sulfamic Acid + BTA cleaning program with HSn70-1A copper tubes.

6. Summary and Recommendations

The core of condenser vacuum recovery lies in timely removal of tube-side fouling resistance, and objective evaluation of cleaning effectiveness must rely on multi-dimensional data—vacuum level, terminal temperature difference, and heat transfer coefficient—not visual appearance alone. For condensers that have operated more than 3 years without cleaning, thorough cleaning should be scheduled as early as possible, with an appropriate cleaning cycle determined based on circulating water quality and seasonal variation patterns.

In terms of cleaning program selection, the combined offline approach of high-pressure water jetting plus chemical cleaning delivers the best recovery results and is ideal for major overhauls or non-heating-season outages. For units requiring continuous operation, an online Sulfamic Acid circulation cleaning program can serve as an interim measure, applied annually to slow the rate of scale accumulation. Post-cleaning passivation must not be omitted—the Na₂CO₃ passivation film is essential protection against rapid secondary oxidation of fresh copper surfaces after cleaning. Establishing a cleaning archive with complete pre- and post-cleaning operational parameters is the foundation for scientific lifecycle management of condensers.

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